By Karl A Gschneidner; ScienceDirect (Online service) (eds.)
This can be the 3rd quantity of a three-volume set of studies dedicated to the interrelationships, similarities, transformations and contrasts of the lanthanide and actinide sequence of parts. It includes 5 chapters at the comparative physics and thermodynamics of the lanthanide and actinide fabrics. the 1st chapters are excited about neutron scattering stories, whereas the subsequent are focused on actual estate stories regarding digital, thermal and magnetic behaviors. the ultimate bankruptcy covers the thermodynamic houses of metal systems.The first bankruptcy compares the inelastic neutron scattering behaviours of the lanthanides and actinides. the subsequent bankruptcy concentrates on neutron scattering through heavy fermion unmarried cyrstal fabrics, together with steel and semiconducting antiferromagnets and approximately insulating paramagnets. bankruptcy 3, essentially the most huge and complete one within the whole sequence, stories intermediate valence and heavy fermions in a large choice of lanthanide and actinide compounds, starting from metal to insulating fabrics. bankruptcy 5 makes a speciality of concerns at the excessive strain behaviors of anomalous cerium, ytterbium and uranium compounds. the ultimate bankruptcy is an intensive assessment of the thermodynamic homes of lanthanide and actinide steel platforms. Read more...
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Additional resources for Handbook on the physics and chemistry of rare earths. Volume 19
5. Raffinose is a trisaccharide, constructed of a galactose–glucose–fructose chain. In its usual crystalline form it contains five water molecules, which give it the configuration shown in the figure. Of the 20 oxygen atoms, five belong to the water molecules of hydration, each of which is hydrogen bonded either to a sugar oxygen or to another water oxygen. The water molecules, although they occupy specific locations in the crystal lattice, are labile in the sense that they can fairly easily be removed and are also subject to fairly rapid exchange with other water molecules.
On the other hand, the mechanisms by which PHCs prevent drying injury has been studied in detail and has also been successfully applied to labile molecules in vitro. The involvement of PHCs in stress tolerance is also of particular scientific interest. Of primary importance is their miscibility with water, coupled with their ease of biodegradation. Their –OH groups closely resemble those of water in energy and conformation, so that hydrogen-bond chains, rings, and networks can be formed, either with the incorporation of water or with its separation.
5° (Kuhs and Lehmann, 1986; Petrenko and Whitworth, 1999). We can thus conclude that there is little strain in this structure and that the hydrogen bonds between neighboring molecules are not far from being linear. What is also evident is the openness of the structure, which is a consequence of the fourfold coordination. It might therefore seem reasonable that ice is less dense than, and hence can float on, water (another of water’s anomalies that can be explained by its molecular properties). Ice, however, can also be found in different phases with different structures as pressure is raised and temperature is varied (Petrenko and Whitworth, 1999; Finney, 2004).