Inorganic reaction mechanisms. : Vol.6 a review of the by Alexander McAuley

By Alexander McAuley

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S. Claesson, Almquist and Wiksell, Stockholm, 1967, p. 437; cited in ref. 26. W. Schmickler and W. Vielstich, Electrochem. Acta, 1973, 18, 883. N. R. Kestner, J. Logan, and J. Jortner, J. Phys. , 1974, 78, 2148. W. Schmickler, Ber. Bunsengesellschaft phys. , 1973, 77, 991. J. Jortner, J. Chem. , 1976, 64, 4860. W. Schmickler, Electrochim. Acta, 1976, 21, 161. J. J. Hopfield, Proc. Nut. Acad. Sci. , 1974, 71, 3640. W. M. Bartczak, J. Kroh, and C. Stradowski, J. Chem. , 1977, 66, 2737. W. Bartczak, J.

66 They include papers on the reaction rates of solvated electron^,^^^ G8 on the conduction properties of metal-ammonia ~ o l u t i o n s ,and ~ ~ on electron mobility in non-polar relevant to the question of possible long-range electron transfer between oxidizing and reducing centres in solution. Measurements of hole mobility and of hole quenching by various reagents in cyclohexane as solvent have been interpreted in terms of electron-transfer reactions such as equation (19) (DMA = NN-dimethylCj’clO-C1#12+ + DMA 4 + C ~ C I O - C ~ DMA+ H~~ (19) aniline).

Elding and L. Gustafson, Znorg. Chim. Acta, (pre-publicationmanuscript kindly supplied by the authors). D. A. Piering and J. M. Malin, J. Amer. Chem. , 1976, 98, 6045. H. E. Toma, J. Inorg. , 1975, 37, 785. Irtorganic Reaction Mechanisms 20 transfer, the first-order specific rate constant being a linear function of the slit width employed in the spectrophotometer. The irradiated band is assigned as FeII-pyrazine (n*)charge transfer. The species formed on excitation is sufficiently reactive to be oxidized by the CoIII centre after virtually every excitation event.

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