Inorganic Syntheses, Volume 14 by Aaron Wold, John K. Ruff

By Aaron Wold, John K. Ruff

The volumes during this carrying on with sequence supply a compilation of present recommendations and concepts in inorganic artificial chemistry. contains inorganic polymer syntheses and guidance of vital inorganic solids, syntheses utilized in the improvement of pharmacologically lively inorganic compounds, small-molecule coordination complexes, and similar compounds. additionally comprises invaluable details on transition organometallic compounds together with species with metal-metal cluster molecules. All syntheses provided the following were validated.

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Extra resources for Inorganic Syntheses, Volume 14

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4. D. L. Schmidt and R. S. patent 3,462,288 (1969). 5. W. W. Wendlant and R. Dunham, Anal. Chim. Acta, 19,505 (1958). 1 1 . TRIMETHYLAMMONIUM TETRAPHENYLBORATE (A Rendy Source of Triphenylborone' ) - 4LiC6H5 + BCl3-ether LiB(C, H5 )4 + (CH3) 3 NHCl LiB(C6H5)4+ ether + 3LiCl (CH3 )3 NHB(C6H5 )4 + LiCl Submitted by K. E. REYNARD,* R. E. SHERMAN,* HAMPTON D. SMITH, JR,* and L. F. HOHNSTEDT* Checked by G. CASSENHEIMERt and T. WARTK? Wittig and co-workers2 have shown that triphenylborane can be readily synthesized in high yield by simple thermal decomposition of trimethylammonium tetraphenylborate.

J. D. dissertation, The Ohio State University, Columbus, Ohio, 1970. 11. G. S. S. thesis, The Ohio State University, 1963; G. S. Benner, W. E. Hatfield, and D. W. Meek, Inorg. , 3. 1544 (1964). 12. B. R. D. dissertation, The Ohio State University, Columbus, Ohio, 1972. 13. G. Kordosky. D. dissertation, The Ohio State University, Columbus, Ohio, 1971. 5. AMIDO(PHOSPHONITRIL1C CHLORIDE-CYCLIC TRIMER) AND 1,l -DIAMIDO(PHOSPHONITRILICCHLORIDECYCLIC TRIMER) MARLENE K. FELDTJ RONALD L. DECK,$ d THERALD MOELLERS Checked by GARY L.

E. Wiberg and R. Uson, Rev. Acad. Cienc. , Fis. Quim. Nat. Zaragoza.. 10(2), 35 (1955). 4. D. L. Schmidt and R. S. patent 3,462,288 (1969). 5. W. W. Wendlant and R. Dunham, Anal. Chim. Acta, 19,505 (1958). 1 1 . TRIMETHYLAMMONIUM TETRAPHENYLBORATE (A Rendy Source of Triphenylborone' ) - 4LiC6H5 + BCl3-ether LiB(C, H5 )4 + (CH3) 3 NHCl LiB(C6H5)4+ ether + 3LiCl (CH3 )3 NHB(C6H5 )4 + LiCl Submitted by K. E. REYNARD,* R. E. SHERMAN,* HAMPTON D. SMITH, JR,* and L. F. HOHNSTEDT* Checked by G. CASSENHEIMERt and T.

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