Materials and Crystallographic Aspects of by M. Marezio, C. Chaillout (auth.), E. Kaldis (eds.)

By M. Marezio, C. Chaillout (auth.), E. Kaldis (eds.)

Superconductors with excessive serious temperatures are super complicated and it continues to be tricky to synthesize prime quality samples. during this regard, the fabrics and crystallographic points, drawing jointly the fields of structural chemistry and physics, stable country chemistry and physics, and purposes and homes, either for cuprate and natural superconductors, play a necessary function in our realizing of the phenomenon. between different issues, the contributions to neighborhood structural elucidation inside the current paintings will shatter the reader's prejudices in regards to the idealized commonplace constitution.

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J. Hathaway, A. W. Hewat: in J. Solid State Chem. 51,364-75. (1984) J. D. Jorgensen, H. Schuttier, D. G. Hinks, D. W. : Phys. Rev. LeU. 581024 (1987) D. E. Cox, A. W. Sleight: Solid State Cornrn. 19969 (1976) R. J. Cava, B. Batlogg, J. J. Krajewski, R. : Nature 332 814 (1988) L. Pauling: J. Am. Chern. Soc. 51 1010 (1929) W. H. Zachariasen: Z. Kristall. 80137 (1931) W. H. Zachariasen: J. Less Cornrnon Metals 62 I (1978) I. D. Brown, D. Alterrnatt: B41 244 (1985) 1. D. Solid State Chern. 82122 (1989) L.

Initially this problem was solved by fitting a number of Gaussians to a group of overlapping peaks, to extract the individual Bragg intensities. The peak shape, being the convolution of a number of instrument parameters is closely approximated by a Gaussian, but more complex functions can be used to account for peak asymmetry, sampie strain etc. The difficulty is that a large number of parameters are required, four for each peak even for a simple Gaussian (position, height, width and background).

Drnowski, B. H. Toby, T. Egami, M. A. : Phys. Rev. LeU. 61 2608 (1988) A. W. Hewat, E. A. Hewat, J. Brynestad, H. A. : Physica C 152 438 (1988) A. W. Hewat, P. Bordet, J. J. Capponi, C. : Physica C 156369 (1988) LOCAL STRUCTURAL DISTORTION : IMPLICATION TO TUE MECHANISM OF IDGU TEMPERATURE SUPERCONDUCTIVITY T. EGAMI Institute for Materials Research, Tohoku University, Sendai 980, Japan, and Department of Materials Science and Engineering and Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia, PA 19104-6272, USA ABSTRACf.

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